Liquid Drops and Globules, Their Formation and Movements Three lectures delivered to popular audiences — Background and Themes

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Darling, Charles R. (Charles Robert), 1870- Project Gutenberg 2011 Not confirmed
Surface tension; Liquids; Drops Readers of public-domain and historical texts
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Words 22,007
Reading time 96 min
Text sections 10

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Three lectures by physicist Charles R. Darling demonstrate surface tension and drop behavior through live experiments, using aniline, chloroform, and water to reveal how liquid spheres form, move, and interact in different media.
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LIQUID DROPS AND GLOBULES

_BY THE SAME AUTHOR._

A Practical Treatise on the Measurement of High Temperatures.

_With 60 Illustrations_, xii + 200 _pp._ _Crown 8vo, cloth_ (1911).

A Treatise on Heat, with special regard to its Practical Applications.

_Second Edition Revised_, with 110 _Illustrations_, xiv + 430 _pp._ _Demy 8vo, cloth_ (1912).

———————————————— _E. & F. N. SPON, Ltd., 57 Haymarket, London, S.W._

LIQUID DROPS AND GLOBULES

Their Formation and Movements

THREE LECTURES DELIVERED TO POPULAR AUDIENCES

ASSOCIATE OF THE ROYAL COLLEGE OF SCIENCE, IRELAND; FELLOW OF THE INSTITUTE OF CHEMISTRY; FELLOW OF THE PHYSICAL SOCIETY, ETC.; LECTURER IN PHYSICS AT THE CITY AND GUILDS OF LONDON TECHNICAL COLLEGE, FINSBURY

WITH 43 ILLUSTRATIONS

_London_ E. & F. N. SPON, LIMITED, 57 HAYMARKET

_NEW YORK_ SPON & CHAMBERLAIN, 123 LIBERTY STREET

PAGE _List of Illustrations_ . . . . . . . vii _Preface_ . . . . . . . . . ix

_Lecture I._ Introduction . . . . . . . . . 1 General Properties of Liquids . . . . . . 2 Properties of the Surface Skin of Water . . . . 3 Elastic Skin of other Liquids-Minimum Thermometer . . . 5 Boundary Surface of two Liquids . . . . . . 6 Area of Stretched Surface . . . . . . . 7 Shape of detached Masses of Liquid . . . . . 8 Production of True Spheres of Liquids . . . . . 10 The Centrifugoscope . . . . . . . . 14 Effect of Temperature on Sphere of Orthotoluidine . . . 15 Other Examples of Equi-Density . . . . . . 17 Aniline Films or Skins . . . . . . . 19 Surface Tension . . . . . . . . 21 The “Diving” Drop . . . . . . . . 22 Formation of Falling Drops of Liquid . . . . . 24 Ascending or Inverted Drops . . . . . . 31

_Lecture II._ Automatic Aniline Drops . . . . . . . 33 Automatic Drops of other Liquids. . . . . . 37 Liquid Jets . . . . . . . . . 38 Liquid Columns . . . . . . . . 40 Communicating Drops . . . . . . . . 44 Combined Vapour and Liquid Drops . . . . . 47 Condensation of Drops from Vapour . . . . . 49 Liquid Clouds in Liquid Media . . . . . . 54 Overheated Drops . . . . . . . . 55 Floating Drops on Hot Surfaces . . . . . . 57

_Lecture III._ Spreading of Oil on the Surface of Water . . . . 60 Movements due to Solubility . . . . . . 63 Movements of Aniline Globules on a Water Surface . . . 63 Movements of Orthotoluidine and Xylidine 1-3-4 on a Water Surface 66 Production of Globules from Films . . . . . 68 Network formed from a Film . . . . . . 70 Quinoline Rings . . . . . . . . 71 Expanding Globules . . . . . . . . 71 Attraction between Floating Globules . . . . . 73 Analogies of Surface Tension Phenomena with Life . . . 75

_Conclusion_ . . . . . . . . . 76

_Appendix_ Apparatus and Materials required for Experiments on Drops and Globules . . . . . . . . 78

_Index_ . . . . . . . . . . 81

LIST OF ILLUSTRATIONS

FIG. PAGE 1. Silver sheet floating on water . . . . . 4 2. Column and index of minimum thermometer . . . 6 3. Thread of golden syrup rising and forming a drop . . 8 4. Drops of different sizes resting on flat plate . . 10 5. Formation of a sphere of orthotoluidine . . . 12 6. Detached sphere floating under water . . . . 13 7. The centrifugoscope . . . . . . . 14 8. Aniline drops falling through cold water and ascending through hot water . . . . . . 17 9. Aniline skins enveloping water . . . . . 20 10, 11, 12. The “diving” drop. Three stages . . . . 23 13. Apparatus for forming ascending or descending drops of liquids 27 14-20. Formation of a drop of orthotoluidine, showing the droplet. Seven stages . . . . . 29-31 21, 22. Automatically

Charles R. Darling opens his first lecture with a direct appeal to observation: he projects a beaker onto a screen so the audience can watch coloured chloroform vapour bubbles rise through water, each dragging a liquid tail. The image of a drop “elongated vertically” because chloroform is denser than water is one of many precise visual cues that structure these three lectures. Darling, a lecturer at the City and Guilds of London Technical College, Finsbury, wrote for popular audiences in 1914, and the text retains the rhythm of a live demonstration—pointing, heating, injecting, and asking listeners to notice.

The Centrifugoscope and True Liquid Spheres

Darling devotes several pages to producing true spheres of liquid, a feat that requires matching the density of the drop to the surrounding medium. He introduces the centrifugoscope, a device that spins a tube of liquid to create artificial gravity, forcing a lighter drop to the centre. The effect of temperature on a sphere of orthotoluidine is shown: as the liquid warms, its density changes, and the sphere drifts. These experiments are not merely decorative; they establish that surface tension alone cannot explain the shapes of drops when buoyancy and rotation intervene. Darling’s method is to isolate one variable—density, temperature, rotation—and let the audience see the result.

Communicating Drops and Reversed Flow

In the second lecture, Darling describes communicating drops: two drops of aniline in water connected by a thin liquid bridge. He notes that the pressure at the base of each drop depends on the height of the column above it, and that these pressures are “numerically very small” yet sufficient to drive flow. By placing the smaller drop at a lower level, he reverses the direction of flow—a feat impossible with soap bubbles in air. This section shows Darling’s skill at making subtle forces visible. He does not claim to have invented the apparatus; instead, he credits the arrangement of liquids of slightly different densities for enabling the reversal.

Combined Vapour and Liquid Drops

A striking experiment in the second lecture involves a coloured layer of chloroform beneath water. When heated, chloroform vapour bubbles rise, each carrying a liquid appendage. Darling points out that the composite drops oscillate vertically: they rise where the water is warm, the vapour expands, then they sink where the water is cold and the vapour condenses. He calls them “weighted balloons.” The practical lesson is that steam from boiling water always contains tiny liquid droplets, a fact familiar to engineers. Darling’s language remains concrete—he describes the drop as “elongated vertically” and notes the vapour bubble’s “lifting power”—without drifting into abstraction.

Movements on a Water Surface

The third lecture turns to drops floating on water. Darling examines the spreading of oil and the movements of aniline globules, orthotoluidine, and xylidine on a water surface. He describes how solubility drives motion: a drop of aniline releases a thin film that alters surface tension, causing the drop to dart. He also shows how globules attract one another, and how a film can break into a network of droplets. The final section, “Analogies of Surface Tension Phenomena with Life,” hints at a broader interpretation, but the excerpts do not reveal how far Darling pursues this analogy. The appendix lists apparatus and materials, confirming that the lectures were designed to be replicated.

Darling’s lectures reward a reader who imagines the laboratory as a theatre. The text is dense with procedural detail—temperatures, densities, injection techniques—but the author never forgets that his audience is watching, not reading equations. To follow the arguments, pause at each described movement: a drop rising, a bubble condensing, a film rupturing. The illustrations (43 in the original) are essential; the text often refers to a figure number. Treat the book as a script for experiments, not a treatise, and the physics becomes visible.

I keep thinking about how Liquid Drops and Globules made something so ordinary—a falling drop—feel almost tender, the way it hesitates before letting go. That same quiet wonder lives in Conversations on Natural Philosophy, in which the Elements of that Science are Familiarly Explained — A Closer Reading, where everything feels like a gentle unfolding rather than a lesson. It stayed with me like a slow breath.

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